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SOLVED:L-Fucose, one of the eight essential monosaccharides (Section 25.7 ), is biosynthesized from GDP-D-mannose by the following three-step reaction sequence, where GDP= guanosine diphosphate (a ribonucleoside diphosphate; Section28.1): (a) Step 1 involves an oxidation to a ketone, a dehydration to an enone, and a conjugate reduction. The step requires NADP^ , but no NADPH is formed as a final reaction product. Propose a mechanism. (b) Step 2 accomplishes two epimerizations and utilizes acidic
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